—L‹@‹à‘®‰»ŠwŒ¤‹†Žº Organometallic Chemistry Laboratory



2022

  1. Enantioselective Synthesis of ƒ¿-Hydroxyamino Ketones by a Chiral Phosphine-Silver Complex Catalyzed N-Nitroso Aldol Reaction
    Yanagisawa, A.; Kasahara, S.;Takeishi, A.; Marui, T.
    Synlett,in press

2021

  1. Asymmetric Aldol Reaction of Alkenyl Esters with ƒ¿-Keto Esters Catalyzed by Chiral Tin Alkoxides
    Yanagisawa, A.; Uchiyama, C.;Takagi, K.
    Synlett,2021,32,2085-2089
  2. Chiral Silver Alkoxide Catalyzed Asymmetric Aldol Reaction of Alkenyl Esters with Isatins
    Yanagisawa, A.; Kawada, A.
    Synlett,2021,32,1246-1252

2020

  1. Selective Propargylation of Diaryl Azo Compounds Using Metallic Barium
    Yanagisawa, A.; Heima, T.; Watanabe, K.; Haeno, S.
    Synlett,2020,31,1817-1822

2019

  1. Asymmetric ƒ¿-Amination Reaction of Alkenoate Cyclic Esters Catalyzed by Chiral Tin Alkoxides
    Yanagisawa, A.; Yamashita, Y.; Uchiyama, C.; Nakano, R.; Horiguchi, M; Ida, K.
    Synlett,2019,738-742

2018

  1. Asymmetric Addition of Propargylic Silanes to Aldehydes Catalyzed by Chiral Phosphine-Silver Alkoxide Complex
    Yanagisawa, A.; Bamba, K.; Kawada, A.
    ChemistrySelect,2018,13777-13781

2017

  1. Asymmetric Allylation of Carbonyl Compounds Catalyzed by a Chiral Phosphine-Silver Complex
    Yanagisawa, A.; Yang, N.; Bamba, K.
    Eur. J. Org. Chem.,2017,6614-6618

2016

  1. Enantio- and Diastereoselective Cross-Annulation of Enal and Ketone with New Chiral Bicyclic
    N-Heterocyclic Carbene Catalysts

    Hasegawa, M.; Yoshida, K.; Yanagisawa, A.
    Chem. Lett.,2016,45,294-296
  2. ƒ¿-Selective Allylation of Isatin Imines Using Metallic Barium
    Yanagisawa, A.; Yamafuji, S.; Sawae, T.
    Synlett.,2016,27,2019-2023
  3. Enantioselective Nitroso Aldol Reaction Catalyzed by a Chiral Phosphine-Silver Complex
    Yanagisawa, A.; Lin, Y.; Takeishi, A.; Yoshida, K.
    Eur. J. Org. Chem.,2016,5355-5359
    Highlighted in SYNFACTS PDF file(127 kb)

2015

  1. Reactive Barium-Promoted Benzylation of Diaryl Azo Compounds
    Yanagisawa, A.; Sawae, T; Yamafuji, S; Heima, T; Yoshida, K.
    Synlett,2015,26,1073-1076
  2. Enantioselective Synthesis of Planar-Chiral Ferrocene-Fused 4-Pyridones and Their Application in Construction of Pyridine-Based Organocatalyst Library
    Ogasawara, M.; Wada, S.; Isshiki, E.; Kamimura, T.; Takahashi, T.; Yanagisawa, A.; Yoshida, K.
    Org.Lett.,2015,17,2286-2289
  3. Chiral Bicyclic NHC/Ir Complexes for Catalytic Asymmetric Transfer Hydrogenation of Ketones
    Yoshida, K.; Kamimura, T.; Kuwabara, H.; Yanagisawa, A.
    Chem. Commun., 2015,51, 15442-15445
  4. Catalytic Enantioselective Synthesis of Chiral 3-Amino-2-oxindoles by a Mannich Approach
    Yanagisawa A.; Kushihara, N.; Sugita, T.; Horiguchi, M.; Ida, K.; Yoshida, K.
    Synlett.,2015, 26, 2541-2546

2014

  1. Asymmetric ƒ¿-Amination Reaction of Alkenyl Trifluoroacetates Catalyzed by a Chiral Phosphine-Silver Compley
    Yanagisawa, A.; Miyake, R; Yoshida, K.
    Org. Biomol. Chem. 2014,12,1935-1941
  2. Catalytic Enantioselective Mannich-Type Reaction via a Chiral Silver Enolate
    Yanagisawa, A.; Lin, Y.; Miyake, R; Yoshida, K
    Org. Lett. 2014,16,86-89
    Highlighted in SYNFACTS PDF file(137 kb)
  3. Asymmetric Aldol Reaction Catalyzed by a Chiral Phosphine-Silver Complex
    Yanagisawa, A.; Miyake, R; Yoshida, K.
    Eur.J.Org.Chem. 2014,4248-4253
    Highlighted in SYNFACTS PDF file(127 kb)
  4. Synthesis of substituted Styrenes and 3-Vinylphenols Using Ruthenium-catalyzed Ring-Closing Enyne Metathesis
    yoshida, K; Nishii, K; Kano, Y; Wada, S; Yanagisawa. A.
    J. Org. Chem. 2014,79,4231-4239

2013

  1. Enantioselective Protonation of Alkenyl Trifluoroacetates Catalyzed by Chiral Tin Methoxide
    Yanagisawa,A.;Sugita, T.; Yoshida, K.
    Chem. Eur. J. 2013,19,16200-16203
  2. Synthesis of 4-Vinylindoles Using Ruthenium-Catalyzed Ring-Closing Enyne Metathesis
    Hayashi, K.; Yoshida, K.; Yanagisawa,A.
    J. Org. Chem. 2013,78(7), 3464-3469
  3. ƒ¿-Selective Allylation of Azo Compounds Using Allylic Barium Reagents
    Yanagisawa, A.; Jitsukawa, T.; Yoshida, K.
    Synlett. 2013,24(5) , 635-639
  4. Development of Asymmetric Reactions Catalyzed by Chiral Organotin-Alkoxide Reagents
    Yanagisawa, T.; Yoshida, K.
    The Chemical Record, 2013,13 , 117-127

2012

  1. Catalytic Enantioselective Synthesis of Chiral Isatin Derivatives by an Aldol Approach
    Yanagisawa, A.; Kushihara, N.; Sugita, T; Yoshida, K
    Synlett. 2012,23 , 1783-1788
  2. Catalytic Enantioselective N-Nitroso Aldol Reaction of ƒÁ,ƒÂ-Unsaturated ƒÂ-Lactones
    Yanagisawa, A.; Fujinami, T.; Oyokawa, Y; Sugita, T; Yoshida, K
    Org. Lett. 2012,14 , 2434-2437 .
  3. Highlighted in SYNFACTS PDF file(149 kb)
  4. Rigid P-Chiral Phosphine Ligands with tert-Butylmethylphosphino Groups for Rhodium-Catalyzed Asymmetric Hydrogenation of Functionalized Alkenes
    Imamoto, T.; Tamura, K.; Zhang, Z; Horiuchi, Y.; Sugiya, M.; Yoshida, K; Yanagisawa, A.; and Ilya D. Gridnev
    J. Am. Chem. Soc. 2012, 134, 1754-1769
  5. Catalytic Asymmetric Cycloaddition Reaction of Alkenyl Trichloroacetate
    Yanagisawa, A.; Izumiseki, A.; Sugita, T.; Kushihara, N.; Yoshida, K.
    Synlett. 2012, 23, 107-112.

2011

  1. Recent Advances in Selective Reactions Promoted by Barium Reagent
    Yanagisawa, A. ;Yoshida, K.
    Synlett. 2011, 13, 2929-2938.
  2. Construction of Carbocyclic Ring of Indoles Using Ruthenium-Catalyzed Ring-Closing Olefin Metathesis
    Yoshida, K.; Hayashi, K.; Yanagisawa, A.
    Org. Lett. 2011, 13, 4762-4765.
  3. Asymmetric Addition of Diethylzinc to Aldehydes Catalyzed by New Zinc-amides Prepared by a Rhodium-catalyzed Asymmetric Addition
    Yoshida, K.; Akashi, N.; Yanagisawa, A.
    Tetrahedron: Asymmetry, 2011, 22, 1225-1230.
  4. Ring Size-Selective Ring-Closing Olefin Metathesis: Taking Advantage of the Deleterious Effect of Ethylene Gas
    Yoshida, K.; Kano, Y.; Takahashi, H.; Yanagisawa, A.
    Adv. Synth. Catal. 2011, 8, 1229-1233.
  5. Catalytic Enantioselective Synthesis of Chiral ƒÁ-Butyrolactones
    Yanagisawa, A.; Kushihara, N.; Yoshida, K.
    Org. Lett. 2011, 13, 1576-1578.
    Highlighted in SYNFACTS PDF file(88 kb)
  6. Synthesis of Biaryl Compounds Using Tandem Ruthenium-Catalyzed Ring-Closing Metathesis
    Yoshida, K.; Shida, H.; Takahashi, H.; Yanagisawa, A.
    Chem. Eur. J. 2011, 17, 344-349.

2010

  1. Dibutylyin Dimethoxide-Catalyzed Cyano Transfer to Aldehydes and Imines
    Yanagisawa, A.; Matsumoto, T. ; Kushihara, N. ; Yoshida, K.
    Adv. Synth. Catal. 2010, 352, 2918-2922.
  2. Enantiopure 1,2-Bis(tert-butylmethylphosphino)benzene as a Highly Efficient Ligand in Rhodium-Catalyzed Asymmetric Hydrogenation
    Tamura, K.; Sugiya, M.; Yoshida, K.; Yanagisawa, A.; Imamoto, T.
    Org. Lett. 2010, 12, 4400-4403.
  3. Selective Propargylation of Azo Compounds with Barium Reagents
    Yanagisawa, A.; Koide, T.; Yoshida, K.
    Synlett 2010, 1515-1518.
  4. Enantioselective Nitroso Aldol Reaction Catalyzed by QuinoxP*-Silver(I) Complex and Tin Methoxide
    Yanagisawa, A.; Takeshita, S.; Izumi, Y.; Yoshida, K.
    J. Am. Chem. Soc. 2010, 132, 5328-5329.
    Highlighted in SYNFACTS PDF file(82 kb)
  5. Bicyclic Imidazoles for Modular Synthesis of Chiral Imidazolium Salts
    Yoshida, K.; Horiuchi, S.; Takeichi, T.; Shida, H.; Imamoto, T.; Yanagisawa, A.
    Org. Lett. 2010, 12, 1764-1767.

2009

  1. Catalytic Asymmetric Three-Component Mannich-Type Reaction of Alkenyl Trichloroacetates
    Izumiseki, A.; Yoshida, K.; Yanagisawa, A.
    Org. Lett. 2009, 11, 5310-5313
  2. Methanol-Assisted Catalysis by Chiral Tin Methoxides: An Alternative Asymmetric Aldol Process
    Yanagisawa, A.; Satou, T.; Izumiseki, A.; Tanaka, Y.; Miyagi, M.; Arai, T.; Yoshida, K.
    Chem. Eur. J. 2009, 15, 11450-11453.
    Highlighted in SYNFACTS PDF file(88 kb)
  3. Synthesis of Substituted Aromatic Compounds Using Ruthenium-Catalyzed Ring-Closing Metathesis
    Yoshida, K.; Imamoto, T.; Yanagisawa, A.
    J. Synth. Org. Chem. Jpn. 2009, 67, 876-888.
  4. Asymmetric Aldol Reaction of Ketones with Alkenyl Trichloroacetates Catalyzed by Dibutyltin Dimethoxide and BINAP¥Silver(I) Complex: Construction of a Chiral Tertiary Carbon Center
    Yanagisawa, A.; Terajima, Y.; Sugita, K.; Yoshida, K.
    Adv. Synth. Catal. 2009, 351, 1757-1762.
    Highlighted in SYNFACTS PDF file(92 kb)
  5. Optically Active Dinuclear Palladium Complexes Containing a Pd-Pd Bond: Preparation and Enantioinduction Ability in Asymmetric Ring-Opening Reaction
    Ogura, T.; Yoshida, K.; Yanagisawa, A.; Imamoto, T.
    Org. Lett. 2009, 11, 2245-2248.
  6. Synthesis of Carbocyclic Aromatic Compounds Using Ruthenium-Catalyzed Ring-Closing Enyne Metathesis
    Takahashi, H.; Yoshida, K.; Yanagisawa, A.
    J. Org. Chem. 2009, 74, 3632-3640.
    selected as a Featured Article
  7. Rapid Screening for Asymmetric Catalysts: the Efficient Connection of Two Different Catalytic Asymmetric Reactions
    Yoshida, K.; Toyoshima, T.; Akashi, N.; Imamoto, T.; Yanagisawa, A.
    Chem. Commun. 2009, 2923-2925.
  8. Dibutyltin Dibromide-catalyzed Trimethylsilylcyanation of Aldehydes and Imines
    Yanagisawa, A.; Matsumoto, T.; Arai, T.; Yoshida, K.
    Chem. Lett. 2009, 336-337.
  9. Dibutyltin Dimethoxide Catalyzed N-Nitrosoaldol Reaction of Alkenyl Trichloroacetate
    Yanagisawa, A.; Izumi, Y.; Takeshita, S.
    Synlett, 2009, 716-719.
  10. Synthesis of 3-Hydroxypyridines Using Ruthenium-Catalyzed Ring-Closing Olefin Metathesis
    Yoshida, K.; Kawagoe, F.; Hayashi, K.; Horiuchi, S.; Imamoto, T.; Yanagisawa, A.
    Org. Lett. 2009, 11, 515-518.

2008

  1. Michael Addition Reaction of Alkenyl Trichloroacetates Catalyzed by Dibutyltin Dimethoxide
    Yanagisawa, A.; Izumi, Y.; Arai, T.
    Chem. Lett. 2008, 1092-1093.
  2. Selective Propargylation of Carbonyl Compounds and Imines with Barium Reagents
    Yanagisawa, A.; Suzuki, T.; Koide, T.; Okitsu, S.; Arai, T.
    Chem. Asian J. 2008, 3, 1793-1800.
  3. Kinetic Resolution of 1,2-Diols Using Nitrogen-Tethered Bisimidazoline-Copper(I) Catalyzed Benzoylation
    Arai, T.; Mizukami, T.; Mishiro, A.; Yanagisawa, A.
    Heterocycles, 2008, 76, 995-1000.
  4. Asymmetric syn-Selective Henry Reaction Catalyzed by Sulfonyldiamine-CuCl-Pyridine System
    Arai, T.; Takashita, R.; Endo, Y.; Watanabe, M.; Yanagisawa, A.
    J. Org. Chem. 2008, 73, 4903-4906.
  5. Organic-Inorganic Hybrid Polymer-Encapsulated Magnetic Nanobeads Catalysts
    Arai, T.; Sato, T.; Kanoh, H.; Kaneko, K.; Oguma, K.; Yanagisawa, A.
    Chem. Eur. J. 2008, 14, 882-885.
  6. A Library of Chiral Imidazoline-Aminophenols: Discovering an Efficient Reaction Sphere
    Arai, T.; Yokoyama, N.; Yanagisawa, A.
    Chem. Eur. J. 2008, 14, 2052-2059.
  7. Recent advances in chiral phosphine-silver(I) complex-catalyzed asymmetric reactions
    Yanagisawa, A.; Arai, T.
    Chem. Commun. 2008, 1165-1172.

2007

  1. Dibutyltin Dimethoxide and BINAP·Silver(I) Complex-Catalyzed Asymmetric Aldol Reaction of Alkenyl Trichloroacetates with Aldehydes
    Yanagisawa, A.; Ichikawa, T.; Arai, T.
    J. Organomet. Chem. 2007, 550-553.
  2. Barium Hydride Promoted Homocoupling and Cross-Coupling Reactions of Enones: An Alternative Entry to Diels-Alder Adducts
    Yanagisawa, A.; Shinohara, A.; Takahashi, H.; Arai, T.
    Synlett, 2007, 141-145.
  3. Salicylhydrazone ligands for enantioselective addition of diethylzinc to aldehydes
    Arai, T.; Endo, Y.; Yanagisawa, A.
    Tetrahedron: Asymmetry, 2007, 18, 165-169.
  4. Reaction Optimization Using Solid Catalysis-CD HTS: Nb-Imidazoline-Cu(I) Catalyzed Asymmetric Benzoylation of meso-1,2-Diols
    Arai, T.; Mizukami, T.; Yanagisawa, A.
    Org. Lett. 2007, 9, 1145-1147.
  5. One-pot synthesis of 1,5-diketones by barium isopropoxide
    Yanagisawa, A.; Takahashi, H.; Arai, T.
    Tetrahedron, 2007, 63, 8581-8585.
  6. Practical Asymmetric Henry Reaction Catalyzed by a Chiral Diamine-Cu(OAc)2 Complex
    Arai, T.; Watanabe, M.; Yanagisawa, A.
    Org. Lett. 2007, 9, 3595-3597.

2006

  1. Quality control of solid-phase synthesis: 13C PST/MAS NMR analysis on non-destructed SynPhase lantern
    Arai, T.; Fujiwara, A,; Watanabe, M.; Yokoyama, N.; Fujito, T.; Deguchi, K.; Yanagisawa, A.
    Tetrahedron Lett. 2006, 47, 1673-1677.
  2. Catalytic Asymmetric Protonation of Lithium Enolates Using Amino Acid Derivatives as Chiral Proton Sources
    Mitsuhashi, K.; Ito, R.; Arai, T.; Yanagisawa, A.
    Org. Lett. 2006, 8, 1721-1724.
  3. Asymmetric Protonation of Silyl Enolates Catalyzed by Chiral Phosphine-Silver(I) Complex
    Yanagisawa, A.; Touge, T.; Arai, T.
    Pure & Appl. Chem. 2006, 78, 519-523.
  4. Dibutyltin Oxide-Catalyzed Allyl-Transfer Reaction to Aldehydes
    Yanagisawa, A.; Aoki, T.; Arai, T.
    Synlett, 2006, 2071-2074.
  5. Direct Monitoring of Asymmetric Induction of Solid Phase Catalysis Using Circular Dichroism
    Arai, T.; Watanabe, M.; Fujiwara, A.; Yokoyama, N.; Yanagisawa, A.
    Angew. Chem. Int. Ed. 2006, 45, 5978-5981.
  6. Direct α-Hydroxylation of Ketones Catalyzed by Organic-Inorganic Hybrid Polymer
    Arai, T.; Sato, T.; Noguchi, H.; Kanoh, H.; Kaneko, K.; Yanagisawa, A.
    Chem. Lett. 2006, 35, 1094-1095.
  7. 1,5-Diketone Synthesis Promoted by Barium Hydride or Barium Alkoxides
    Takahashi, H.; Arai, T.; Yanagisawa, A.
    Synlett, 2006, 2833-2835.

2005

  1. Enantioselective Protonation of Silyl Enolates Catalyzed by a Binap·AgF Complex
    Yanagisawa, A.; Touge, T.; Arai, T.
    Angew. Chem. Int. Ed. 2005, 44, 1546-1548.
  2. Regioselective Propargylation of Carbonyl Compounds with (3-bromoprop-1-ynyl)trimethylsilane Promoted by Reactive Barium
    Yanagisawa, A.; Okitsu, S.; Arai, T.
    Synlett, 2005, 1679-1682.
  3. Mannich-Type Reaction Using Alkenyl Trichloroacetates Catalyzed by Dibutyltin Dimethoxide
    Yanagisawa, A.; Saito, H.; Harada, M.; Arai, T.
    Adv. Synth. Catal. 2005, 347, 1517-1522.
  4. Design and Synthesis of a Chiral N-tethered Bis(imidazoline) Ligand
    Arai, T.; Mizukami, T.; Yokoyama, N.; Nakazato, D.; Yanagisawa, A.
    Synlett, 2005, 2670-2672.
  5. Catalytic Synthesis of ƒ¿-Hydroxy Ketones Using Organic-Inorganic Hybrid Polymer
    Arai, T.; Takasugi, H.; Sato, T.; Noguchi, H.; Kanoh, H.; Kaneko, K.; Yanagisawa, A.
    Chem. Lett. 2005, 12, 1590.

2004

  1. Selective Synthesis of α,β-Unsaturated Ketones by Dibutyltin Dimethoxide-Catalyzed Condensation of Aldehydes with Alkenyl Trichloroacetates
    Yanagisawa, A.; Goudu, R.; Arai, T.
    Org. Lett. 2004, 6, 4281-4283.
  2. Reactive Barium-Promoted Reformatsky-Type Reaction of α-Chlororketones with Aldehydes
    Yanagisawa, A.; Takahashi, H.; Arai, T.
    Chem. Commun. 2004, 580-581.
  3. α-Amino Acid-Promoted Asymmetric Allylation of Aldehydes with Allylstannanes
    Yanagisawa, A.; Nakamura, Y.; Arai, T.
    Tetrahedron Asymmetry, 2004, 15, 1909-1913.

2003

  1. Dibutyltin Dimethoxide-Catalyzed Aldol Reaction of Enol Trichloroacetate
    Yanagisawa, A.; Sekiguchi, T.
    Tetrahedron Lett. 2003, 44, 7163-7166.